Evaluating The Electrochemical Performance Of Graphite And Silicon-Based Materials In Energy Storage Device
Keywords:
Sodium-ion battery, graphene oxide, silicon dioxide, composite, anode material, cycling stability
Abstract
Sodium-ion batteries (SIBs) have emerged as a promising alternative to lithium-ion batteries (LIBs) since sodium resources are more abundant, and their utilization is cheaper. However, their application is limited by the problem of obtaining high energy density and stable cycling in the long term. In the following study, we discuss usage of silicon dioxide (SiO₂) and graphene oxide (GO) to overcome these issues. Comparative Cyclic voltammetry, Galv. current density, energy density and capacity density measurement between pure GO, SiO₂ and GO-SiO₂ composites for SIB configurations. GO was found to have good conductivity and improved Na-ion transport but cycling stability was moderate. SiO₂ showed ordinary cycling stability but lower initial capacity as compared to the composite material. The incorporation of SiO₂ in the structure of the GO material has a synergistic effect where both the GO high conductivity and the structure stability of SiO₂ and therefore improved sodium-ion storage capability and long-term cycling stability. From these conclusions, it can be proposed that GO-SiO 2 composites can be promising materials for practical applications of SIBs as an efficient anode with sufficiently high capacity and conductivity.
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2. Bie, X., Xiong, M., Wang, B., Dong, Y., Chen, Z., & Huang, R. (2022, January 1). Glucose hydrothermal encapsulation of carbonized silicone polyester to prepare anode materials for lithium batteries with improved cycle stability. Royal Society of Chemistry, 12(15), 9238-9248. https://doi.org/10.1039/d2ra00960a
3. Cao, L., Wu, H., Yan, P., He, X., Li, J., Li, Y., Xu, M., Qiu, M., & Jiang, Z. (2018, October 11). Graphene Oxide‐Based Solid Electrolytes with 3D Prepercolating Pathways for Efficient Proton Transport. Wiley, 28(50). https://doi.org/10.1002/adfm.201804944
4. Chu, Z., Zhao, X., Wang, Q., Bao, T., Li, H., Cao, Y., Zhang, B., Cao, J., & Si, W. (2023, March 22). Preparation of a Flexible Reduced Graphene Oxide-Si Composite Film and Its Application in High-Performance Lithium Ion Batteries. Multidisciplinary Digital Publishing Institute, 13(3), 547-547. https://doi.org/10.3390/cryst13030547
5. Cong, R., Park, H., Jo, M., Lee, H., & Lee, C. (2021, August 10). Synthesis and Electrochemical Performance of Electrostatic Self-Assembled Nano-Silicon@N-Doped Reduced Graphene Oxide/Carbon Nanofibers Composite as Anode Material for Lithium-Ion Batteries. Multidisciplinary Digital Publishing Institute, 26(16), 4831-4831. https://doi.org/10.3390/molecules26164831
6. Dashairya, L., Das, D., & Saha, P. (2020, August 15). Binder-free electrophoretic deposition of Sb/rGO on Cu foil for superior electrochemical performance in Li-ion and Na-ion batteries. Elsevier BV, 358, 136948-136948. https://doi.org/10.1016/j.electacta.2020.136948
7. Eftekhari, A., & Kim, D. (2018, June 15). Sodium-ion batteries: New opportunities beyond energy storage by lithium. Elsevier BV, 395, 336-348. https://doi.org/10.1016/j.jpowsour.2018.05.089
8. Fang, L., Bahlawane, N N., Sun, W G., Pan, H M., Xu, B B., Yan, M Z., & Jiang, Y. (2021, July 30). Conversion-Alloying Anode Materials for Sodium Ion Batteries. https://onlinelibrary.wiley.com /doi/10.1002/smll.202101137
9. Gao, R., Tang, J., Yu, X., Zhang, K., Ozawa, K., & Qin, L. (2020, January 1). A green strategy for the preparation of a honeycomb-like silicon composite with enhanced lithium storage properties. Royal Society of Chemistry, 12(24), 12849-12855. https://doi.org/10.1039/d0nr02769c
10. Gong, D., Wei, C., Liang, Z., & Tang, Y. (2021, May 5). Recent Advances on Sodium‐Ion Batteries and Sodium Dual‐Ion Batteries: State‐of‐the‐Art Na+ Host Anode Materials. https://onlinelibrary.wiley.com/doi/ pdfdirect/10.1002/smsc.20210001
11. Guan, B., Qi, S., Li, Y., Sun, T., Liu, Y., & Yi, T. (2020, June 17). Towards high-performance anodes: Design and construction of cobalt-based sulfide materials for sodium-ion batteries. Elsevier BV, 54, 680-698. https://doi.org/10.1016/j.jechem.2020.06.005
12. Guo, X., Xu, H., Li, W., Liu, Y., Shi, Y., Li, Q., & Pang, H. (2022, December 5). Embedding Atomically Dispersed Iron Sites in Nitrogen‐Doped Carbon Frameworks‐Wrapped Silicon Suboxide for Superior Lithium Storage. Wiley, 10(4). https://doi.org/10.1002/advs.202206084
13. Huang, H., Silva, K D., Kumara, G., & Yoshimura, M. (2018, April 25). Structural Evolution of Hydrothermally Derived Reduced Graphene Oxide. Nature Portfolio, 8(1). https://doi.org/10.1038/s41598-018-25194-1
14. Huang, Z., Dang, G., Jiang, W., Sun, Y., Meng, Y., Zhang, Q., & Xie, J. (2021, January 25). A Low‐Cost and Scalable Carbon Coated SiO‐Based Anode Material for Lithium‐Ion Batteries. WileyOpen, 10(3), 380-386. https://doi.org/10.1002/open.202000341
15. Jo, M., Sim, S., Kim, J., Oh, P., & Son, Y. (2022, June 7). Micron-Sized SiOx-Graphite Compound as Anode Materials for Commercializable Lithium-Ion Batteries. Multidisciplinary Digital Publishing Institute, 12(12), 1956-1956. https://doi.org/10.3390/nano12121956
16. Li, C., Li, C., Jiang, T., Ma, Y., Yang, Y., Liu, J., & Hao, C. (2020, July 5). Enhanced sodium storage in strongly-combined MoS2/rGO nanocomposite: Constructed by ionic liquid induced layer-by-layer self-assembly. Elsevier BV, 354, 136646-136646. https://doi.org/10.1016/j.electacta.2020.136646
17. Nie, B., Sánchez, D., Alcoutlabi, M., Liu, T., Basu, S., Kumara, S., Wang, G., & Sun, H. (2023, January 1). Regulating the size and assembled structure of graphene building blocks for high-performance silicon nanocomposite anodes. Royal Society of Chemistry, 2(9), 1381-1389. https://doi.org/10.1039/d3ya00203a
18. Tian, F., Pang, Z., Hu, S., Zhang, X., Wang, F., Nie, W., Xia, X., Li, G., Hsu, H., Xu, Q., Zou, X., Li, J., & Lu, X. (2023, January 1). Recent Advances in Electrochemical-Based Silicon Production Technologies with Reduced Carbon Emission. American Association for the Advancement of Science, 6. https://doi.org/10.34133 /research.0142
19. Wang, J., Xu, Z., Zhang, Q., Song, X., Lu, X., Zhang, Z., Onyianta, A J., Wang, M., Titirici, M., & Eichhorn, S J. (2022, September 21). Stable Sodium‐Metal Batteries in Carbonate Electrolytes Achieved by Bifunctional, Sustainable Separators with Tailored Alignment. , 34(49). https://doi.org/10.1002/adma.202206367
20. Zhang, W., Zhang, F., Ming, F., & Alshareef, H N. (2019, July 29). Sodium-ion battery anodes: Status and future trends. Elsevier BV, 1(2), 100012-100012. https://doi.org/10.1016/j.enchem.2019.100012
21. Zhang, Y., Tang, Y., Li, X., Liu, H., Wang, Y., Xu, Y., & Du, F. (2022, August 15). Porous Amorphous Silicon Hollow Nanoboxes Coated with Reduced Graphene Oxide as Stable Anodes for Sodium-Ion Batteries. American Chemical Society, 7(34), 30208-30214. https://doi.org/10.1021/acsomega.2c03322
22. Zhao, L., Zhang, T., Zhao, H., & Hou, Y. (2020, January 17). Polyanion-type electrode materials for advanced sodium-ion batteries. Elsevier BV, 10, 100072-100072. https://doi.org/10.1016/j.mtnano.2020.100072
23. Zhou, X., Qi, Z., Liu, Q., Tian, J., Liu, M., Dong, K., & Lei, Z. (2021, January 22). Research Progress of Silicon Suboxide-Based Anodes for Lithium-Ion Batteries. Frontiers Media, 7. https://doi.org/10.3389 /fmats.2020.628233
Published
2023-12-25
How to Cite
Pawan D. Somavanshi, & Yogesh U. Sathe. (2023). Evaluating The Electrochemical Performance Of Graphite And Silicon-Based Materials In Energy Storage Device. Revista Electronica De Veterinaria, 24(4), 474-479. https://doi.org/10.69980/redvet.v24i4.1277
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